The duo are expected to be joined by model Elen Rives, soap star Alex Ferns, Russell Grant, Nancy Dell'Olio and Carol Smillie, reports the Daily Star.
Former tabloid editor Kelvin MacKenzie, TV presenter Donna Air and Coronation Street actress Tupele Dorgu are also rumoured to be taking part.
Kitchen Burnout will feature celebrities competing against each other and in challenges such as cooking for jockey Frankie Dettori, Chelsea FC and a private members' club. Hell's Kitchen star Marco Pierre White will oversee the contestants' progress on the programme.
The show is expected to air on ITV1 next month.