The 'Gimme All Your Luvin'' singer will be interviewed by Dan Wootton, to be spread across both Daybreak and Lorraine on Friday (April 20).
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Wootton revealed that it will be Madonna's only UK interview this summer as she promotes her latest album MDNA.
In a short clip ahead of next week's broadcast, Madonna revealed what she does and doesn't miss about living in the UK.
"I miss riding my bike everywhere, I miss the British sense of humour," she said. "What [do] I miss the least? The congestion charge."
Madonna will talk about a range of subjects including her thoughts on Catherine, Duchess of Cambridge, Adele and motherhood.
The entertainer is rumoured to be releasing 'Turn Up the Radio' as her next single from MDNA.
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Watch the video for Madonna's 'Girl Gone Wild' below: