The legendary singer is to perform a selection of Christmas classics for a one-off ITV programme in December.
Rod Stewart's Christmas Special will be filmed at Scotland's Stirling Castle, with an air date still to be announced.
Kylie Minogue, Michael Bublé and violinist Nicola Benedetti will also appear for collaborations with the veteran star.
Stewart said: "Christmas comes early for me this year. I'm really looking forward to singing with Kylie and Michael and performing with Nicola.
"The show will be a real seasonal treat."
The show will support Stewart's upcoming festive album Merry Christmas, Baby, released on October 30.
The LP will include collaborations with Michael Bublé, Cee Lo Green and Mary J Blige among others.