Brosnan and Melissa George (Hunted) star in the US TV adaptation of Stephen King's award-winning thriller, which will get its UK premiere in December.
Rolf's Animal Christmas tops the entertainment lineup, a one-off spinoff from Rolf's Animal Clinic, which was a ratings hit for the broadcaster.
Other TV highlights include a new Celebrity Wedding Planner featuring EastEnders stars John Partridge and Nina Wadia and a festive treat for Eddie Stobart fans with a Christmas Cracker edition of the trucker show.
An Audience With Ken Dodd, TV's 50 Greatest Magic Tricks, Most Shocking Celebrity Moments 2012 and Tommy Cooper's Christmas will also air across the Christmas period.
Channel 5 will welcome in the year with a new series of Celebrity Big Brother.
Emma Willis and Brian Dowling return to host the latest edition of the long-running reality show, which starts back in the first week of January.