The former England goalkeeper, who was in the bottom two last week, and the TV magician are the favourites to become the second celebrity eliminated from the BBC One show.
Shilton has odds of 6/4, while punters can bet on Daniels at 9/4. Patsy Kensit (8/1) and Michelle Williams (12/1), who have had mixed responses from the judges in the first couple of weeks of the competition, are also potentially running the risk of being voted off.
Despite finishing at the bottom of the judges' leaderboard, Ann Widdecombe has relatively long odds of 12/1 that she will depart this week.
Strictly airs at 6pm on Saturday on BBC One.