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Writing on her Twitter blog from the Channel 4 show's wrap party, McCall described the duo as "friends with benefits".
She said: "I got the impression Tom and Noirin are a couple!"
Afterwards, she added: "Tom and Noirin are friends with benefits! Poor Siavash! I know! I think Tom wants more!"
Kelly was pursued romantically by Sree Dasari, Marcus Akin and Siavash Sabbaghpour while inside the house, but reunited with American ex-boyfriend Isaac Stout when he joined the show halfway through. However, the Dubliner confirmed on the Big Brother final night that she had since split from Stout.
Tom walked out of the house on Day 53, describing appearing on the show as being "part of a circus".
McCall confirmed that winner Sophie Reade was not dating Kris Donnelly and revealed that finalist David Ramsden had arranged a meeting with fashion icon Vivienne Westwood.
She also suggested that Marcus Akin should be given his own TV or radio show.
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