It has also been confirmed that the show's four coaches - will.i.am, Sir Tom Jones, Jessie J and Danny O'Donoghue - will be reuniting for a group performance of U2's 'Beautiful Day'. The foursome last performed together in the first Blind Auditions episode when they sang Black Eyed Peas' 'I Gotta Feeling'.
The full songlist for Saturday's live show is below:
Joelle Moses - I'm Going Down (Mary J Blige)
Sophie Griffin - Titanium (David Guetta feat Sia)
Jaz Ellington - At Last (Etta James)
Frances Wood - Ain't Nobody (Chaka Khan)
Tyler James - Higher Love (James Vincent McMorrow)
Sam Buttery - A Little Respect (Erasure)
Matt and Sueleen - Go Your Own Way (Fleetwood Mac)
Leanne Mitchell - Who Knew (Pink)
Adam Isaac - All My Life (Foo Fighters)
Ruth Brown - Get Here (Oleta Adams)
Two acts - one from each team - will be voted off the reality show on Sunday's results show.
Jessie J and Danny O'Donoghue's acts will perform in week two.
The Voice UK's first live show airs at 7pm on BBC One.