Contestants will be performing covers of artists including Elvis Presley, Coldplay, Kate Bush and Cheryl Cole.
Coaches Jessie J and Danny O'Donoghue will see their five final acts perform live for the first time since making it though the battle rounds on Saturday.
The full songlist for Saturday's live show is as follows:
Max Milner - Free Fallin' (Tom Petty)
Bo Bruce - Running Up That Hill (Kate Bush)
Hannah Berney - Cry Me A River (Julie London/Justin Timberlake mash-up)
Aleks Josh - Dream A Little Dream Of Me (Mama Cass)
David Julien - Sweet Disposition (The Temper Trap)
Ruth-Ann St. Luce - Promise This (Cheryl Cole)
Becky Hill - Good Luck (Basement Jaxx)
Cassius Henry - Paradise (Coldplay)
Toni Warne - Proud Mary (Creedence Clearwater Revival/Tina Turner)
Vince Kidd - Always On My Mind (Brenda Lee/Elvis Presley)
Two acts - one from each team - will be voted off the reality show on Sunday's results show.
The Voice UK airs tomorrow (May 5) at 7.10pm on BBC One.