The show, a reboot of the original '70s series, stars Annie Ilonzeh, Minka Kelly and Rachael Taylor as a trio of glamorous crime-fighters.
The drama, which also stars Ramon Rodriguez as Bosley, is due to premiere in the US next month and will receive its UK premiere on E4.
"Charlie's Angels is a light-hearted, high-kicking romp with all the glitz, glamour and beautiful crime-fighters you would expect from a US remake of the iconic original," said Channel 4's head acquisitions Gill Hay. "E4 viewers can look forward to some hot Miami action as part of our brand new lineup."
It was recently reported that original Charlie's Angels stars Jaclyn Smith and Cheryl Ladd could make guest appearances on the new show.
Channel 4 has picked up the rights to a number of forthcoming US series in recent weeks, including live-action comedies 2 Broke Girls and The New Girl, animated series Napoleon Dynamite and Allen Gregory, and political thriller Homeland.
> Michael Rosenbaum hoping for 'Charlie's Angels' role
Watch a trailer for the new Charlie's Angels below: