The Breaking Bad star will take the stage at next month's awards show. It was previously hosted by Parks and Recreation star Nick Offerman.
Cranston is also nominated for the 'Individual Achievement In Drama' award for his performance in Breaking Bad.
Homeland leads the nominations with four nods, while Mad Men and Breaking Bad received three nominations apiece.
The fifth and final season of Breaking Bad will premiere July 15 at 10pm on AMC.
The Television Critics Association Awards will be held on July 28 during the TCA press tour.
> Breaking Bad season five poster unveiled: "All hail the king"
Watch a trailer for Breaking Bad season five below: