VH1 Storytellers features artists sharing the inspiration for their greatest hits while performing acoustically.
Swift will kick off the series's new season on November 11, with Keys's episode being broadcast one day later on November 12. VH1 Storytellers: Pink airs on November 13.
Pink spoke of her excitement at appearing on VH1 Storytellers in an interview with Entertainment Weekly.
"I have always loved Storytellers and, as a songwriter, how much fun it is to be able to tell your stories," the 'Raise Your Glass' singer said.
VH1 Storytellers premiered in February 1996 with Ray Davies of The Kinks playing many of the group's classic tracks.
The Bee Gees, Stevie Nicks, David Bowie, Christina Aguilera, Cee Lo Green, Foo Fighters and Kanye West have been guest stars on the music series in the last 16 years.
Watch Taylor Swift's 'We Are Never Ever Getting Back Together' lyrical music video below: