Rihanna and Bieber will be making their first appearances on the annual lingerie showcase, with Bruno Mars also on hand for a special live performance.
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Alessandra Ambrosio, Lily Aldridge, Miranda Kerr, Adriana Lima, and Behati Prinsloo are all expected to strut the catwalk at the Fashion Show.
Last year's fashion show featured performances from Nicki Minaj, Jay-Z, Maroon 5 and Kanye West.
The 2012 Victoria's Secret Fashion Show will be held in New York City for the fourth year in a row.
CBS broadcasts the special event on Tuesday, December 4 at 10/9c.
Watch Kanye West perform on the Victoria's Secret Fashion Show below:
