The Unapologetic singer will produce and star in the US version, airing on the Style Network in 2013.
"Fashion has always played an integral part in my life and career," Rihanna shared in a statement.
"I am so excited to partner with Style Network and share my creative insight with these 12 designers, and give them this opportunity to showcase their work."
Similar to the UK format, the US's Styled to Rock will feature up-and-coming designers who will be creating pieces for Hollywood stars.
Th UK's Styled to Rock premiered on Sky Living in August and crowned Zainab Vandu-Chikolo as the season one winner in October.
Watch a trailer for Styled to Rock UK below: