The poster shows lead character Walter White (Bryan Cranston) sitting in a warehouse with piles of cash by his sides, featuring the tagline "All hail the king".
Breaking Bad's fifth season will be split into two equal parts of eight episodes each.
Cranston previously explained how the series will shoot the upcoming run.
"We're going to shoot the first eight, then take a four-month production break, then the rest will air next year," he said.
Last month, AMC announced that Breaking Bad will broadcast the first half of the season on Sunday, July 15 at 10pm ET and the second half will air in summer 2013.
Watch the trailer for Breaking Bad's fourth season below: