In a similar vein to shows such as Glee and American Idol, NBC's new series will release songs performed by the cast members and guest stars.
The 1960s drama centres around Hugh Hefner's Playboy Club in Chicago and will premiere tonight.
The first episode will feature versions of Frank Sinatra's 'Chicago (That Toddlin' Town)' by Laura Benanti and Ike & Tina Turner's 'Shake a Tail Feather' by Karen LeBlanc.
Colbie Caillat, Raphael Saadiq and The Voice winner Javier Colon will appear as guest stars during the first season, with tributes to the likes of Roy Orbison, Frank Sinatra and James Brown.
20th Century Fox Television have teamed up with Verve Music Group, a division of Universal Music Group, to release the weekly songs to iTunes.
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Watch a trailer for The Playboy Club below: