Trucco is set to play Nate, who is described as "the street-smart, charismatic and slightly menacing brother of new Hamptons resident Kenny", reports TVLine.
The ABC drama follows Emily VanCamp as a woman who returns to the Hamptons in order to seek revenge on those who framed her father for a crime he didn't commit.
Trucco is best known for his role on the sci-fi series Battlestar Galactica. He also starred in Sarah Shahi's legal series Fairly Legal on the USA network.
His previous television credits include How I Met Your Mother and Psych.
Season two of Revenge airs on Sunday at 9pm ET on ABC. The show airs on E4 in the UK.