The series - co-created by Supernatural's Eric Kripke - is set in a future world in which all forms of energy have mysteriously ceased to exist.
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© NBC Universal
Mark Pellegrino will appear in the show's third episode as a militia leader, TVLine reports.
The 47-year-old actor played Lucifer on Supernatural and is also known for his roles on Lost and Syfy's Being Human.
Child actor Colin Ford - who plays the young Sam Winchester (Jared Padalecki) - joins Revolution in episode four as a young boy kidnapped by the militia, while Todd Stashwick - who appeared in a 2008 Supernatural episode - will play a drug lord in episode six.
Revolution premiered on NBC on Monday night (September 17), attracting 11.65 million viewers. The series continues this Monday at 10/9c.
> Revolution review: Does JJ Abrams's new sci-fi drama burn bright?
Watch the stars of Revolution discuss the show with Digital Spy below:
